Title of article
Synthesis and Structural Characterization of Cationic Rhenium(V) and Technetium(V) Dioxo Complexes Containing Four N-Heterocyclic Carbene Ligands
Author/Authors
Zahn، Theresa I. نويسنده , , Braband، Henrik نويسنده , , Abram، Ulrich نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-615
From page
616
To page
0
Abstract
Cationic dioxorhenium and dioxotechnetium complexes of the composition [MO2(L1)4]+ (L1 = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) have been prepared from various starting materials and studied spectroscopically and by X-ray crystallography. The metal-carbon distances range from 2.216(4) to 2.232(4) (angstrom) indicating mainly (sigma)-bonding.
Keywords
Oscillations , Methane oxidation , Complete oxidation , Metal catalysts , Partial oxidation
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
67236
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