Title of article
Diels-Alder Reactions of Styrylcyclohexenones: an Efficient Procedure for the Synthesis of Substituted Dehydrodecaline Derivatives
Author/Authors
M. Saeed Abaee، نويسنده , , Mohammad M. Mojtahedi، نويسنده , , M. Taghi Rezaei، نويسنده , , Hamid Reza Khavasi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
6
From page
605
To page
610
Abstract
The Diels-Alder reaction of styrylcyclohex-2-enone derivatives 1 with N-phenylmaleimide was shown to be an efficient pathway for the synthesis of substituted dehydrodecaline derivatives. At elevated temperatures, mixtures of endo/exo adducts were formed, while in the presence of TiCl4 exclusive formation of the endo stereoisomer was observed. Spectroscopic analysis and X-ray crystallography confirmed the formation of the endo adducts.
Keywords
dehydrodecalines , Cycloaddition , Styrylcyclohexenone dienes , Lewis acid catalysis , Diels-Alder reaction
Journal title
Acta Chimica Slovenica
Serial Year
2011
Journal title
Acta Chimica Slovenica
Record number
672406
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