Mechanochemical and solution reactions between AgCH3COO and [H2NC6H10NH2] yield three isomers of the coordination network {Ag[H2NC6H10NH2]+}(infinity)

Solid-state co-grinding of silver acetate and solid trans-1,4-diaminocyclohexane, [H2NC6H10NH2] yields two isomeric coordination networks depending on the crystallization conditions; a third isomeric form is obtained when the same reaction is carried out in solution.