Title of article
On the kinetics and energetics of one-electron oxidation of 1,3,5-triazines
Author/Authors
Azenha، M. E. D. G. نويسنده , , Burrows، H. D. نويسنده , , L.، M. Canle نويسنده , , Coimbra، R. نويسنده , , Fern?ndez، M. I. نويسنده , , Garc?a، M. V. نويسنده , , Rodrigues، A. E. نويسنده , , Santaballa، J. A. نويسنده , , Steenken، S. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-111
From page
112
To page
0
Abstract
One-electron oxidation of 1,3,5-triazines is observed with both excited uranyl ion (*UO22+) and sulfate radical anion (SO4.– ) in aqueous solution, but not with Tl2+, indicating that the standard reduction potentials E° of 1,3,5-triazine radical cations are ~~2.3 ± 0.1 V vs. NHE, consistent with theoretical calculations; this suggests that if triazines inhibit electron transfer during photosynthesis, they would need to act on the reductive part of the electron transport chain.
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68160
Link To Document