Author/Authors :
Li، Guanghua نويسنده , , Wang، Qing Mei نويسنده , , Liu، Xiaoyang نويسنده , , Sun، Licheng نويسنده , , Akermark، Bjorn نويسنده , , Wang، Fujun نويسنده , , Jin، Kun نويسنده , , Dong، Weibing نويسنده ,
Abstract :
The complex [{((mu)-SCH2)2N(CH2C6H4-2-Br)}Fe2(CO)6] and its N-protonated species, as structural models of the Fe-only hydrogenase active site, were identified spectroscopically and crystallographically, and their molecular structures show the 0.04–0.1 (angstrom) lengthening of the three N–C bonds and an intramolecular H...Br contact (2.82 (angstrom)) in the crystalline state of the N-protonated species.
