Title of article
Chirality transfer during alkylation of chiral amides
Author/Authors
Chen، Jianyong نويسنده , , Kawabata، Takeo نويسنده , , Ozturk، Orhan نويسنده , , Fuji، Kaoru نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-161
From page
162
To page
0
Abstract
Chiral amides derived from O-methyl mandelic acid and achiral amines underwent enantioselective alpha-methylation on treatment with LTMP followed by addition of methyl iodide; chirality transfer from an undeprotonated chiral amide into an achiral enolate in a mixed aggregate is supposed to be responsible for the asymmetric induction.
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68244
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