Title of article :
Chirality transfer during alkylation of chiral amides
Author/Authors :
Chen، Jianyong نويسنده , , Kawabata، Takeo نويسنده , , Ozturk، Orhan نويسنده , , Fuji، Kaoru نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Pages :
-161
From page :
162
To page :
0
Abstract :
Chiral amides derived from O-methyl mandelic acid and achiral amines underwent enantioselective alpha-methylation on treatment with LTMP followed by addition of methyl iodide; chirality transfer from an undeprotonated chiral amide into an achiral enolate in a mixed aggregate is supposed to be responsible for the asymmetric induction.
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year :
2003
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number :
68244
Link To Document :
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