Author/Authors :
Howard، Judith A. K. نويسنده , , Osipov، Alexander L. نويسنده , , Vyboishchikov، Sergei F. نويسنده , , Dorogov، Konstantin Y. نويسنده , , Kuzmina، Lyudmila G. نويسنده , , Lemenovskii، Dmitrii A. نويسنده , , Nikonov، Georgii I. نويسنده ,
Abstract :
The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (JH–Si= 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane (sigma)-complex Cp*(iPr3P)Ru(Cl)((eta)^2HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl...SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.
