Title of article :
Mechanistic studies on the asymmetric alkylation of amino ester enolates using a copper(II)salen catalyst
Author/Authors :
Banti، Donatella نويسنده , , Belokon، Yuri N. نويسنده , , Fu، Wen-Lan (Steffy) نويسنده , , Groaz، Elisabetta نويسنده , , North، Michael نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Hammett data indicate that the asymmetric alkylation of enolates catalysed by copper(II)salen complex 1, proceeds by an asynchronous SN2 reaction and that the role of the catalyst is to enhance the nucleophilicity of the enolate.
Keywords :
molecular processes , ISM: molecules , molecular data
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
