Title of article
Spontaneous chiral resolution of a coordination polymer with distorted helical structure consisting of achiral building blocks
Author/Authors
Neumann، Beate نويسنده , , Stammler، Hans-Georg نويسنده , , Siemeling، Ulrich نويسنده , , Scheppelmann، Imke نويسنده , , Stammler، Anja نويسنده , , Frelek، Jadwiga نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2235
From page
2236
To page
0
Abstract
Reaction of achiral 2,5-diphenyl-3,4-di(3-pyridyl)cyclopenta-2,4-dien-1-one (2) with ZnCl2 and HgBr2, respectively, afforded the helically chiral coordination polymers [(2)ZnCl2](infinity) and [(2)HgBr2](infinity), which show spontaneous chiral resolution, forming colonies of homochiral crystals.
Keywords
Model diagnosis , Goodness of fit , Restricted latent class models , Identifiability , Parametric bootstrap
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69131
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