• Title of article

    Spontaneous chiral resolution of a coordination polymer with distorted helical structure consisting of achiral building blocks

  • Author/Authors

    Neumann، Beate نويسنده , , Stammler، Hans-Georg نويسنده , , Siemeling، Ulrich نويسنده , , Scheppelmann، Imke نويسنده , , Stammler، Anja نويسنده , , Frelek، Jadwiga نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -2235
  • From page
    2236
  • To page
    0
  • Abstract
    Reaction of achiral 2,5-diphenyl-3,4-di(3-pyridyl)cyclopenta-2,4-dien-1-one (2) with ZnCl2 and HgBr2, respectively, afforded the helically chiral coordination polymers [(2)ZnCl2](infinity) and [(2)HgBr2](infinity), which show spontaneous chiral resolution, forming colonies of homochiral crystals.
  • Keywords
    Model diagnosis , Goodness of fit , Restricted latent class models , Identifiability , Parametric bootstrap
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69131