Title of article :
A quasi-covalent metal–metal bond in an early–late heterobimetallic Ti–Pt complex stabilized by phosphinoenolate ligands
Author/Authors :
Braunstein، Pierre نويسنده , , Morise، Xavier نويسنده , , Welter، Richard نويسنده , , Rohmer، Marie-Madeleine نويسنده , , Benard، Marc نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
An unusual early–late bimetallic complex with direct metal–metal bonding is obtained from a phosphinoenolate ligand-assisted reaction between Ti(IV) and Pt(0) reagents which occurs by formal insertion of the Pt(0) centre into a Ti(IV)–O bond; X-ray data and EHMO calculations indicate the presence of a quasi-covalent Ti(III)–Pt(I) bond (2.721(2) ?).
Keywords :
Mellin transform , Brownian motion , Riemann zeta function , gamma process , Bessel process , characterization of distributions , Meixner process , Levy process
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
