Title of article
Synthesis of novel palladium OCN-pincer complexes: unprecedented sequential C(sp^3)–H activation and aerobic oxidation in the reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3
Author/Authors
Solans، Xavier نويسنده , , Font-Bardia، Merce نويسنده , , Sole، Daniel نويسنده , , Vallverd?، Lluis نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2737
From page
2738
To page
0
Abstract
The reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3 under O2 gives palladium OCN-pincer complexes by means of an unprecedented process that involves the formal aerobic oxidation of C(sp^3)–H bonds at the (alpha)position of the aniline N atom.
Keywords
ISM: molecules , molecular processes , molecular data
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69164
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