Title of article :
The truly symmetrical doubly-bridging mode of trimethylphosphine in a dinuclear rhodium complex
Author/Authors :
Werner، Helmut نويسنده , , Pechmann، Thomas نويسنده , , Brandt، Carsten D. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The dinuclear complex [Rh2I2(µ-CPh2)2(µ-PMe3)] was prepared from the Rh2(acac)2 counterpart and Me3SiI and shown crystallographically to contain the PMe3 ligand in a truly symmetrical bridging position; a new synthetic route to migrate more bulky phosphines such as PPh3 and PiPr3 from a terminal into a bridging site is also described.
Keywords :
Brownian motion , Mellin transform , Riemann zeta function , characterization of distributions , gamma process , Levy process , Meixner process , Bessel process
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
