• Title of article

    Isolation of electronic from geometric contributions to Bergman cyclization of metalloenediynes

  • Author/Authors

    Pink، Maren نويسنده , , Clark، Aurora E. نويسنده , , Zaleski، Jeffrey M. نويسنده , , Bhattacharyya، Sibaprasad نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -1155
  • From page
    1156
  • To page
    0
  • Abstract
    Conformationally constrained ethylene-diamine metalloenediyne compounds exhibit alkyne termini separations that are constant and independent of metal center geometry. Ancillary chloride ligand electron donation into the Bergman cyclization reaction coordinate, however, dramatically influences the observed temperatures.
  • Keywords
    Meixner process , Riemann zeta function , Mellin transform , characterization of distributions , Brownian motion , Bessel process , gamma process , Levy process
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69282