Title of article
A diiron complex mediates an intramolecular aliphatic hydroxylation by various oxygen donors
Author/Authors
Latour، Jean-Marc نويسنده , , Dubois، Lionel نويسنده , , Avenier، Frederic نويسنده , , Dubourdeaux، Patrick نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-47
From page
48
To page
0
Abstract
In the presence of hydrogen peroxide, m-chloroperbenzoic acid or an iodosyl arene, the tert-butyl group of the ligand H (L–t-Bu) in the complex [Fe2(L–t-Bu)(mpdp)]^2+ is quantitatively hydroxylated to a butanolate terminally bound to one iron in [Fe2(L–t-Bu – H + O)(mpdp)]^2+, and mass spectrometry experiments indicate that the reaction proceeds according to different mechanisms.
Keywords
Spurgia esulae , Biological control , Invasive weeds , Endangered species , Aphthona flava , Aphthona czwalinae , Aphthona lacertosa , Aphthona nigriscutis , Euphorbia esula , Leafy spurge flea beetles , IPM
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69298
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