Title of article
Acyclic amino acid-catalyzed direct asymmetric aldol reactions: alanine, the simplest stereoselective organocatalyst
Author/Authors
Zou، Weibiao نويسنده , , Ibrahem، Ismail نويسنده , , Cordova، Armando نويسنده , , Reyes، Efraim نويسنده , , Engqvist، Magnus نويسنده , , Liao، Wei-Wei نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-3585
From page
3586
To page
0
Abstract
The linear amino acid-catalyzed direct asymmetric intermolecular aldol reaction is presented; simple amino acids such as alanine, valine, isoleucine, aspartate, alanine tetrazole 3 and serine catalyzed the direct catalytic asymmetric intermolecular aldol reactions between unmodified ketones and aldehydes with excellent stereocontrol and furnished the corresponding aldol products in up to 98% yield and with up to > 99% ee.
Keywords
molecular data , ISM: molecules , molecular processes
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69356
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