Title of article :
Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination
Author/Authors :
Kumagai، Naoya نويسنده , , Matsunaga، Shigeki نويسنده , , Shibasaki، Masakatsu نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The cooperative catalysis of CpRu(PPh3)2(CH3CN)PF6(1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding (beta)-hydroxynitriles 3 in good yield.
Keywords :
ISM: molecules , molecular processes , molecular data
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
