Title of article
Potassium-zinc induced synergic enhancement of the basicity of hexamethyldisilazide (HMDS) towards methylbenzene molecules
Author/Authors
Clegg، William نويسنده , , Kennedy، Alan R. نويسنده , , Mulvey، Robert E. نويسنده , , Forbes، Glenn C. نويسنده , , Liddle، Stephen T. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-405
From page
406
To page
0
Abstract
While neither KHMDS nor Zn(HMDS)2 can unilaterally metallate toluene under the conditions studied, the bilateral base ʹKZn(HMDS)3ʹ can smoothly do so to produce the benzyl product [{KZn(HMDS)2(CH2Ph)}(infinity)], which exists in the crystal as an infinite spiral chain of benzyl (ambi-(sigma), (pi))-linked (KNZnN) rings.
Keywords
galaxies: Local Group , star: formation , galaxies: individual: LMC , galaxies: ISM , galaxies: irregular , galaxies: Magellanic Clouds
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69526
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