Title of article
Regioselective silylphosphination of methyl vinyl ketone with complexes containing cyclic and linear iron– silicon–phosphorus reacting sites
Author/Authors
Tobita، Hiromi نويسنده , , Okazaki، Masaaki نويسنده , , Jung، Kyeong A نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-911
From page
912
To page
0
Abstract
Treatment of Cp*(CO)Fe{(kappa)^2(Si,P)-SiMe2PPh2} with methyl vinyl ketone gave a 1,2-addition product, Cp*(CO)Fe{(kappa)^2(Si,P)-SiMe2OCMe(CH=CH2)PPh2}. A linear-type Cp*(CO)2FeSiMe2PPh2 also reacted with the ketone to yield a 1,4-addition product, Cp*(CO)2Fe{(kappa)^1(Si)-SiMe2OC(Me)=CHCH2PPh2}, which was further converted to a seven-membered metallacycle, Cp*(CO)Fe{(kappa)^2(Si,P)-SiMe2OC(Me)=CHCH2PPh2}, upon photolysis.
Keywords
Aphthona nigriscutis , Aphthona flava , Aphthona lacertosa , Euphorbia esula , Spurgia esulae , Invasive weeds , IPM , Endangered species , Biological control , Aphthona czwalinae , Leafy spurge flea beetles
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69539
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