Title of article
Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions
Author/Authors
Kennedy، Alan R. نويسنده , , Mulvey، Robert E. نويسنده , , Hevia، Eva نويسنده , , OHara، Charles T. نويسنده , , Andrikopoulos، Prokopis C. نويسنده , , Armstrong، David R. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1130
From page
1131
To page
0
Abstract
Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu4^2– dianions within a polycationic network, is reported.
Keywords
Aphthona lacertosa , Aphthona nigriscutis , Leafy spurge flea beetles , Spurgia esulae , Biological control , IPM , Endangered species , Invasive weeds , Aphthona flava , Aphthona czwalinae , Euphorbia esula
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69707
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