• Title of article

    Double-twist Mobius aromaticity in a 4n+ 2 electron electrocyclic reaction

  • Author/Authors

    Rzepa، Henry S. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -521
  • From page
    522
  • To page
    0
  • Abstract
    One transition state for the 10 electron (4n+ 2) electrocyclisation of Z,E,Z-decapentaene is predicted to have the properties of a double-twist Mobius strip, with delocalised bond lengths and the NICS(0) magnetic index typical of aromaticity; a 5,6-di-tBu substituted decapentaene is predicted to react in this mode in preference to the competitive sixelectron electrocyclisation.
  • Keywords
    molecular processes , molecular data , ISM: molecules
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2005
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69756

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=69756