Title of article
An unexpected bonding interaction between dxy and a1u orbitals mediated by porphyrin deformation
Author/Authors
Cheng، Ru-Jen نويسنده , , Wang، Yen-Ku نويسنده , , Chen، Ping-Yu نويسنده , , Han، Ya-Ping نويسنده , , Chang، Chih-Ching نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1311
From page
1312
To page
0
Abstract
Through density functional calculation and NMR spectroscopy, an unusual intermediate-spin electronic structure (dxzdyz)3(dxy)1(dz2)1 has been assigned to the six-coordinate saddled [Fe(OETPP)(THF)2]+ complex instead of the corresponding ruffled [Fe(TiPrP)(THF)2]+ complex.
Keywords
PLAYBACK EXPERIMENTS , TONIC COMMUNICATION , URGENCY-BASED , VIGILANCE
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70044
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