Title of article :
An unexpected bonding interaction between dxy and a1u orbitals mediated by porphyrin deformation
Author/Authors :
Cheng، Ru-Jen نويسنده , , Wang، Yen-Ku نويسنده , , Chen، Ping-Yu نويسنده , , Han، Ya-Ping نويسنده , , Chang، Chih-Ching نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Through density functional calculation and NMR spectroscopy, an unusual intermediate-spin electronic structure (dxzdyz)3(dxy)1(dz2)1 has been assigned to the six-coordinate saddled [Fe(OETPP)(THF)2]+ complex instead of the corresponding ruffled [Fe(TiPrP)(THF)2]+ complex.
Keywords :
PLAYBACK EXPERIMENTS , TONIC COMMUNICATION , URGENCY-BASED , VIGILANCE
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
