Title of article
Stabilisation of an ortho-deprotonated mesityl group within the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P} Sn]^3– stannate ion
Author/Authors
McPartlin، Mary نويسنده , , Wright، Dominic S. نويسنده , , Woods، Anthony D. نويسنده , , Pask، Christopher M. نويسنده , , Vogler، Thomas نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1523
From page
1524
To page
0
Abstract
The reaction of 2,4,6-Me3C6H2PHNa with Sn(NMe2)2(3 : 1 equivalents, respectively) results in the formation of the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]^3– stannate trianion in the heterometallic cage [{2,4,6-Me3C6H2P}{4,6Me2C6H2(2-CH2)P}Sn]Na3·2TMEDA]4(1), in which unprecedented ortho-Me deprotonation of a [2,4,6-Me3C6H2P]^2– ligand has occurred.
Keywords
atmospheric VOC , isoprene oxidation , inhibition of S(IV) autoxidation , isoprene , Sulphur dioxide
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70173
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