Title of article
Snapshots of an oxidatively induced (alpha)-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide
Author/Authors
Basuli، Falguni نويسنده , , Huffman، John C. نويسنده , , Mindiola، Daniel J. نويسنده , , Bailey، Brad C. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1553
From page
1554
To page
0
Abstract
One electron oxidation of the bis-anilido titanium(III) complex (Nacnac)Ti(NHAr)2(Nacnac–= ArNC(CH3)CHC(CH3)NAr, Ar= 2,6-(CHMe2)2C6H3) with AgOTf affords the cation [(Nacnac)Ti(NHAr)2][OTf] which is isolated and shown to gradually transform, by (alpha)-hydrogen abstraction, to the terminal and four-coordinate titanium imide (Nacnac)Ti=NAr(OTf).
Keywords
atmospheric VOC , isoprene , Sulphur dioxide , isoprene oxidation , inhibition of S(IV) autoxidation
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70219
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