Title of article :
Palladium-catalyzed, stereoselective rearrangement of a tetracyclic allyl cyclopropane under arylation
Author/Authors :
Yao، Min-Liang نويسنده , , Storsberg، Jorg نويسنده , , Ocal، Nuket نويسنده , , Meijere، Armin de نويسنده , , Adam، Arnold E. W. نويسنده , , Kaufmann، Dieter E. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The first example of a (pi),(sigma) domino-Heck reaction under concomitant rearrangement of the tetracyclic allylcyclopropane endo,exo-bishomobarrelene (5) is reported; the stereoselective reaction proceeds via an intramolecular insertion of a primarily-formed carbopalladation intermediate into a strained cyclopropane C–C (sigma)-bond, giving 9.
Keywords :
molecular data , molecular processes , ISM: molecules
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
