Title of article
Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes
Author/Authors
Wilson، Claire نويسنده , , Arnold، Polly L. نويسنده , , Rodden، Mark نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1742
From page
1743
To page
0
Abstract
Alkoxide-functionalised N-heterocyclic carbenes (NHCs) stabilise the potassium-imidazole-2-ylidene fragment against 1,2 alkyl rearrangement reactions; this allows the first structural characterisation of a potassium NHC complex, which reveals distorted and unusual bonding interactions between the imidazole ring and the potassium cation.
Keywords
Synthesis of (beta)-amino alcohols , Titanosilicate molecular sieves , Aminolysis of epoxides , Ti-MCM-41
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70316
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