Title of article
Reduction of alkynes into 1,2-dideuterioalkenes with hexamethyldisilane and deuterium oxide in the presence of a palladium catalyst
Author/Authors
Hayashi، Tamio نويسنده , , Shirakawa، Eiji نويسنده , , Otsuka، Hidehito نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-5884
From page
5885
To page
0
Abstract
A combination of hexamethyldisilane and deuterium oxide was found to work as a deuterium transfer reagent for alkynes in the presence of a catalytic amount of a palladium complex to give (E)-1,2-dideuterioalkenes selectively through the corresponding (Z)-isomer.
Keywords
molecular data , molecular processes , ISM: molecules
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70422
Link To Document