• Title of article

    Synthesis of a simplified analogue of eleutherobin via a Claisen rearrangement and ring closing metathesis strategy

  • Author/Authors

    Bond، Andrew D. نويسنده , , Holmes، Andrew B. نويسنده , , Chiang، Gary C. H. نويسنده , , Ayscough، Andrew نويسنده , , Pain، Gilles نويسنده , , Ducki، Sylvie نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -185
  • From page
    186
  • To page
    0
  • Abstract
    The enantioselective synthesis of a simplified eleutherobin analogue 7 by ring closing metathesis (RCM) of the 2,9-divinyl-substituted tetrahydro-oxonin 5 is described; the analogue 7 and an advanced intermediate 15 revealed microtubule stabilising properties in the micromolar range.
  • Keywords
    Aminolysis of epoxides , Synthesis of (beta)-amino alcohols , Ti-MCM-41 , Titanosilicate molecular sieves
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2005
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    70428