Title of article
A low temperature cluster condensation approach to CdS nanocrystals: oxidative aggregation of [Cd10S4Br4(SR)12] 4– with sulfur
Author/Authors
Osterloh، Frank E. نويسنده , , Hewitt، Daniel P. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-16
From page
17
To page
0
Abstract
The cluster salt [N(C2H5)4]4[Cd10S4Br4(Sp-Tol)12] reacts with six equivalents of sulfur in dimethylformamide at 140 °C to produce polycrystalline (wurtzite type) CdS nanoparticles of 5.8 nm mean diameter, which on their surface are ligated with ptolylthiolate ligands, dimethylformamide and water; UV/vis, PL, 1H- and 113Cd-NMR spectra recorded during various stages of the synthesis indicate that the CdS nanoparticles are formed by a cluster condensation process.
Keywords
atmospheric VOC , inhibition of S(IV) autoxidation , isoprene , isoprene oxidation , Sulphur dioxide
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70493
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