Title of article
Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution
Author/Authors
Richard، John P. نويسنده , , Chiang، Yvonne نويسنده , , Kresge، A. Jerry نويسنده , , Onyido، Ikenna نويسنده , , Wan، Peter نويسنده , , Xu، Musheng نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-4230
From page
4231
To page
0
Abstract
Photodecarboxylation of p-benzoylphenylacetic acid in aqueous solution produces the elongated enol 5, whose strength as an oxygen acid (pQEa= 7.67) makes it more acidic than simple enol analogs by several orders of magnitude.
Keywords
Titanosilicate molecular sieves , Synthesis of (beta)-amino alcohols , Ti-MCM-41 , Aminolysis of epoxides
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70713
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