Title of article :
Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidine
Author/Authors :
Hutchings، Graham J. نويسنده , , Arx، Matthias von نويسنده , , Dummer، Nicholas نويسنده , , Willock، David J. نويسنده , , Taylor، Stuart H. نويسنده , , Wells، Richard P. K. نويسنده , , Wells، Peter B. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Pt supported on (alpha)-Al2O3, (gamma)-Al2O3 and SiO2 pre-modified with cinchonidine gives over 50% ee in the hydrogenation of methyl pyruvate to methyl lactate using gas phase reactants at 40 °C giving the first clear observation of high enantioselection at the gas/solid interface.
Keywords :
isoprene oxidation , Sulphur dioxide , isoprene , inhibition of S(IV) autoxidation , atmospheric VOC
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
