Title of article :
A facile and novel route to unprecedented manganese C4 cumulenic complexes
Author/Authors :
Fox، Thomas نويسنده , , Fernandez، Francisco J. نويسنده , , Berke، Heinz نويسنده , , Schmalle، Helmut W. نويسنده , , Venkatesan، Koushik نويسنده , , Blacque، Olivier نويسنده , , Alfonso، Montserrat نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe){=C=C=C=C(SnPh3)2} was obtained by photolysis of the Csp2–Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh3)–C(identical)CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn–C4–SnPh3.
Keywords :
atmospheric VOC , inhibition of S(IV) autoxidation , isoprene , Sulphur dioxide , isoprene oxidation
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
