Title of article
A facile and novel route to unprecedented manganese C4 cumulenic complexes
Author/Authors
Fox، Thomas نويسنده , , Fernandez، Francisco J. نويسنده , , Berke، Heinz نويسنده , , Schmalle، Helmut W. نويسنده , , Venkatesan، Koushik نويسنده , , Blacque، Olivier نويسنده , , Alfonso، Montserrat نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2005
From page
2006
To page
0
Abstract
The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe){=C=C=C=C(SnPh3)2} was obtained by photolysis of the Csp2–Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh3)–C(identical)CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn–C4–SnPh3.
Keywords
atmospheric VOC , inhibition of S(IV) autoxidation , isoprene , Sulphur dioxide , isoprene oxidation
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70750
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