Title of article
Dithiocarbamyl-substituted diphosphanylmethanide complexes of manganese(I): a new type of ambivalent metalloligands
Author/Authors
Garcia-Granda، Santiago نويسنده , , Riera، Victor نويسنده , , Ruiz، Javier نويسنده , , Quesada، Roberto نويسنده , , Diaz، M. Rosario نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2027
From page
2028
To page
0
Abstract
The diphosphanylmethanide complex [Mn(CO)4{(PPh2)2C–H}] promotes S–S bond breaking in tetramethylthiuram disulfide affording [Mn(CO)4{(PPh2)2C–S–C(S)NMe2}](2), which proved to be a valuable host for binding cations through the methanide carbon atom and the thiocarbonyl group, allowing the controlled synthesis of heterometallic compounds.
Keywords
atmospheric VOC , inhibition of S(IV) autoxidation , isoprene oxidation , isoprene , Sulphur dioxide
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70760
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