Title of article
Supported cationic complexes: selective preparation and characterization of the well-defined electrophilic metallocenium cation [(identical)SiO–B(C6F5)3]–[Cp*ZrMe2(Et2NPh)]+ supported on silica
Author/Authors
Basset، Jean-Marie نويسنده , , Millot، Nicolas نويسنده , , Santini، Catherine C. نويسنده , , Baudouin، Anne نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2033
From page
2034
To page
0
Abstract
The reaction of Cp*ZrMe3, 1, with the heterogeneous activator [(identical)SiO–B(C6F5)3]–[HNEt2Ph]+, 2, has been investigated to generate, by an irreversible process of methane elimination, the well-defined cationic silica-supported metallocenium species [(identical)SiO–B(C6F5)3]–[Cp*ZrMe2(NEt2Ph)]+, 3, as an active olefin polymerisation catalyst.
Keywords
atmospheric VOC , inhibition of S(IV) autoxidation , Sulphur dioxide , isoprene , isoprene oxidation
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70763
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