Title of article
An unprecedented mode of ligation for a bridged amido-cyclopentadienide (constrained geometry) ligand; (pi)-olefinic interactions with gallium and indium
Author/Authors
Jones، Jamie N. نويسنده , , Cowley، Alan H. نويسنده , , Wiacek، Robert J. نويسنده , , Pietryga، Jeffrey M. نويسنده , , Mullins، Lucille A. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2071
From page
2072
To page
0
Abstract
The surprising reaction of GaCl3 or InBr3 with the di-Grignard reagent [Me2Si(C5Me4)(N-t-Bu)](MgCl)2·THF results in salts of the bimetallic anions of composition [X3M{C5Me4(N-t-Bu)}MX2]–(M = Ga, X = Cl; M = In; X = Br) in which the MX2 moiety undergoes an (eta)2-interaction with one of the double bonds of the localized cyclopentadienide ring.
Keywords
inhibition of S(IV) autoxidation , Sulphur dioxide , isoprene , isoprene oxidation , atmospheric VOC
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70782
Link To Document