Abstract :
A synthetic scheme for the solid-phase synthesis of unprecedented polythioether dendrons has been established, the dendrons prepared up to the fourth generation, and the applicability of the dendronized resins for supported catalysis has been demonstrated.
Keywords :
Regiochemistry , Alicyclic Aliphatic Substrates , stereochemistry , Triorganylstannyl , (alpha)Carbon , Cycloalkyl Halides , Aliphatic Substrates , Carbonylation , Nitroalkanes , Carbanions , Nitrogen Nucleophiles , Sulfur Nucleophiles , Phosphorus Nucleophiles , Nitrobenzyl , sp2 Carbons , Cumyl , Radicals Intermediates , Trihalides , Oxygen , sp3 Carbons , Heterocyclic Analogues , Photostimulated Reactions , Geminal Dihalides , EWG , Neopentyl