Formation of chlorinated aromatic compounds in the raw gas of waste incineration plants

Selected experiments were performed at the TAMARA waste incineration pilot plant with a view to identify the formation mechanism of chlorinated aromatic compounds during dust separation by fabric filters at temperatures above 200°C. Significant formation of chlorinated aromatic compounds studied from precursors possibly contained in the flue gas could not be proven in the experiments performed. Formation of chlorinated aromatic compounds was compared with carbon conversion in the filter cake. According to balancing, the fraction of converted carbon that is found in the chlorinated aromatic compounds amounts to a few percent a temperature of 240°C and is constant in the first approximation. Chlorinated aromatic compounds are generated from the fine particulate residual carbon of the fly ashes. Therefore, a de-novo synthesis has to be postulated as mechanism.