Decomposition of nitrous oxide on pillared clays

Alumina-pillared smectites have been found to abate nitrous oxide in the presence of methane. The results indicate that the yield of the reaction (N2O→N2+(1/2)O2) increases when pillared clays are exchanged with transition metals, single-pass conversion rates of >70% being attainable. In particular, when double exchanged (calcium and subsequently copper) alumina pillared montmorillonite/beidellite is used as a catalyst, de-N2O activity reaches a maximum, which is maintained even after 4 h of work at a space velocity of 5.5 h−1. A mechanism for the reaction is suggested, which implies that N2O is first adsorbed by the catalyst and then decomposes through two different paths: catalyst oxidation and catalyst reduction. Such a redox process explains the kinetic data.