Title of article :
Biodegradation of a nonylphenol ethoxylate by the autochthonous microflora in lake water with observations on the influence of light
Author/Authors :
Reinier M. Mann، نويسنده , , Michael R. Boddy، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
Alkylphenol polyethoxylates (APE) are routinely used as additives in pesticide formulations. Biodegradation of APEs results in the accumulation of persistent short chain mono-, di- and tri-ethoxylates (AP1EO, AP2EO AP3EO) that are more toxic than the parent compounds and potentially oestrogenic. Accumulation of persistent APE metabolites in shallow or ephemeral waters may pose a hazard to aquatic fauna. This study has followed the degradation and formation of individual oligomers in freshwater in static die-away tests with and without illumination. Over 33 days in darkness there was a progressive and complete loss of long chain oligomers (NP8-17EO), transient increases and subsequent loss of short to medium chain oligomers (NP4-7EO), and large persistent increases ( 1000%) in short chain oligomers (NP1-3EO). In the presence of illumination, biodegradation was retarded and heterotrophic bacterial proliferation was inhibited. After 33 days there was complete loss of long chain oligomers (NP9-17EO), incomplete loss of medium chain oligomers (NP6-8EO) and increases in short chain oligomers (NP1-5EO).
Keywords :
surfactant , Alkylphenol polyethoxylate , Bacterial degradation , HPLC , Static die-away
Journal title :
Chemosphere
Journal title :
Chemosphere