Title of article :
Characterization of lead, cadmium, arsenic and nickel in PM2.5 particles in the Athens atmosphere, Greece
Author/Authors :
Nikolaos S. Thomaidis، نويسنده , , Evangelos B. Bakeas، نويسنده , , Panayotis A. Siskos، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Pages :
8
From page :
959
To page :
966
Abstract :
Concentrations of Pb, Cd, As and Ni in PM2.5 particles were measured in samples collected, using low volume PM2.5 samplers (Harvard Impactor system, HI) at two sites in Athens basin; Patission Street in Athens city center and Rentis, a semi-urban and industrial area, during March 1995–March 1996. Sample analysis for Pb, Cd, Ni and As was accomplished by electrothermal atomic absorption spectrometry after total digestion. Annual geometric mean values in 183 PM2.5 particles samples were found to be: Pb: 143 ng m−3; Cd: 0.34 ng m−3; Ni: 4.55 ng m−3; As: 0.79 ng m−3. The geographical and temporal distribution patterns were investigated. Pb exhibited higher values during the winter period. For the other elements no significant seasonal variation was observed. Wind direction, air temperature and relative humidity affected element concentrations. Principal component analysis was applied on the data to enable source apportionment of toxic elements in PM2.5 particles. It was found that Pb, As and Ni have common sources, which could be vehicles emissions/oil combustion and resuspended road dust. Cd and a portion of As originate from industrial activities.
Keywords :
Atmospheric aerosol , Meteorology , Principal component analysis , Toxic metals , Sources
Journal title :
Chemosphere
Serial Year :
2003
Journal title :
Chemosphere
Record number :
736802
Link To Document :
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