Photodegradation of chlorinated pesticides dispersed on sand

The photochemical behaviour of several chlorinated pesticides, namely 4-chloro-2-methylphenoxyacetic acid (MCPA), dichlorophen (DCPH), flamprop-methyl (FPM) and vinclozolin (VCZ) is studied on various kinds of sand: Fontainebleau sand (almost pure silica), Touggourt sand (coloured sand from Sahara) and Jijel sand (dark marine sand).The photodegradation of MCPA is more rapid on Fontainebleau sand than on the two others, because the former is almost colourless pure silica and the others adsorb on the internal surface of the reactor. The degradation rate decreases in the order MCPA, DCPH, FPM, VCZ. The main products identified are 4-chloro-2-methylphenol with MCPA and reduction product with DCPH.