A natural analogue for the long-term corrosion of copper nuclear waste containers—reanalysis of a study of a bronze cannon

The study of natural analogues is often used to support long-term predictions of the safety of geological disposal of used nuclear fuel. The case of a bronze cannon, submerged in seawater-saturated clay sediments for a period of 310 a, is reassessed with reference to a corrosion mechanism developed for copper nuclear waste containers in a conceptual disposal vault in the Canadian Shield. Redox reactions between Cu, Fe and dissolved O2 are believed to have played an important role in the corrosion of the bronze cannon and also form an essential part of the corrosion mechanism proposed for nuclear waste containers. Limited rates of mass transport through compacted clay are also important in determining the corrosion behaviour of both the cannon and the containers.