Potentiometrically measured Eh in groundwaters from the Scandinavian Shield

Measurement and interpretation of electrochemical Eh values in natural reducing groundwaters is a complex task. SKB, the company in charge of disposal of nuclear fuel wastes in Sweden, has developed a refined methodology for the determination of this parameter in packered sections in boreholes. The methodology consists of the simultaneous use of three different electrodes (Pt, Au and C) both at depth and at the surface, and maintaining continuous logging over a long period of time. Apart from Eh, the logging also includes other parameters such as pH, dissolved O2, conductivity and temperature. This methodology has been used since the 80s in the framework of the hydrogeochemical characterisation programs supported by SKB at different sites in the Scandinavian Shield. All the existing databases have been revisited in this work using a uniform set of criteria to select Eh values of the Swedish groundwaters as a function of depth.