Real-time characterization of ultrafine and accumulation mode particles in ambient combustion aerosols

The diffusion charging sensor (DC), photoelectric aerosol sensor (PAS) and condensation particle counter (CPC) are real-time particle instruments that have time resolutions <10 s and are suitable for field use. This paper shows how the relative fraction of nuclei mode particles (D 50 nm) in ambient combustion aerosols can be determined, along with the coverage degree of the respective accumulation mode particles with a modal diameter of 100 nm. Main tools for interpretation are the diameter of average surface DAve,S (obtained from CPC and DC measurements) and PAS/DC versus DAve,S scatter plots. Compared to the scanning mobility particle sizer (SMPS), which is a standard instrument for aerosol particle size distribution measurements, the presented method has a limited accuracy, but is substantially faster. Additionally, it is experimentally less demanding than SMPS measurements, especially for field applications.