Long-term changes of inorganic nutrients in the Lagoon of Venice (Italy)

The paper aims at investigating the trends of the concentrations of dissolved inorganic nitrogen (DIN) and phosphorous in the Lagoon of Venice, Italy, in the last 35 years. The trend analysis of ammonia nitrogen, nitrate nitrogen and reactive phosphorus (RP) yielded rather different results. The decrease in ammonia nitrogen concentration, in particular, in the basin influenced by severe industrial discharges, is accurately described by a negative exponential model. The nitrate concentration did not show significant interannual trends, while wide seasonal variations have been detected. Reactive phosphorus concentration increased until the end of the 1970s at the stations close to the industrial area as well as in those influenced by river discharges and by sewages of the city of Venice. The sudden decrease that followed was most likely related with environmental policies, namely the improvement of wastewater purification treatments and the regulation of phosphorus use in detergents.