Sulfide removal in wastewater from petrochemical industries by autotrophic denitrification

An alternative flowchart for the biological removal of hydrogen sulfide from oil-refining wastewater is presented; autotrophic denitrification in a multi-stage treatment plant was utilized. A pilot-scale plant was fed with a mixture of the following constituents: (a) original wastewater from an oil refining industry (b), the effluent of the existing nitrification-stage treatment plant and (c) sulfide in the form of Na2S. Anoxic sulfide to sulfate oxidation, with nitrate as a terminal electron acceptor, proved very successful, as incoming concentrations of 110 mg S2−/L were totally converted to SO42−. At complete denitrification, the concentration of S2− in the reactor effluent was less than 0.1 mg/L. Fluctuating S2− concentration in the feed could be tolerated without any problems, as the accumulated sulfide in the effluent of the denitrification stage is oxidized aerobically in a subsequent activated-sludge treatment stage. This alternative new treatment scheme was further introduced at the refineryʹs wastewater processing plant. Thus, complete H2S removal is now accomplished by the combination of the proposed biological method and the existing stripping with CO2. As a result, stripping, and thus its cost, is reduced by 70%.