Title of article :
Asymmetric hydroformylation with highly crosslinked polystyrene-supported (R,S)-BINAPHOS–Rh(I) complexes: the effect of immobilization position
Author/Authors :
Fumitoshi Shibahara، نويسنده , , Kyoko Nozaki، نويسنده , , Takeshi Matsuo، نويسنده , , Tamejiro Hiyama، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
A new class of polymer-supported (R,S)-BINAPHOS 1e in which the parent BINAPHOS has two alkoxy-substituents at the 3-positions of the phenyls, has been synthesised. Using its Rh(I) complex, asymmetric hydroformylation of olefins proceeded with higher enantioselectivity in some cases compared to the conventional polymer-supported 1c.
Journal title :
Bioorganic & Medicinal Chemistry Letters
Journal title :
Bioorganic & Medicinal Chemistry Letters
