Title of article :
Observations on the reactivity of thiyl radicals derived from 3,6-epidithiodiketopiperazine-2,5-diones and related congeners
Author/Authors :
S.T. Hilton، نويسنده , , W.B. Motherwell، نويسنده , , P. Potier، نويسنده , , C. Pradet، نويسنده , , D.L. Selwood، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
A range of thiyl radicals derived from the reduced form of epidithiodiketopiperazines (ETPs) act as polarity reversal catalysts for the hydrosilylation of an enol lactone but not for H-atom abstraction from a model ribose ester.
Keywords :
Thiyl radicals , Epidithiodiketopiperazines , Polarity reversal catalysis , Mechanism , DNA cleavage
Journal title :
Bioorganic & Medicinal Chemistry Letters
Journal title :
Bioorganic & Medicinal Chemistry Letters
