Dielectric properties of Pb[(1-x)(Zr1/2Ti1/2)-x(Zn1/3Ta2/3)]O3 ceramics prepared by columbite and wolframite methods

Polycrystalline samples of Pb[(1 - x)(Zr1/2Ti1/2) - x(Zn1/3Ta2/3)]O3, where x = 0.1–0.5 were prepared by the columbite and wolframite methods. The crystal structure, microstructure, and dielectric properties of the sintered ceramics were investigated as a function of composition via X-ray diffraction (XRD), scanning electron microscopy (SEM), and dielectric spectroscopy. The results indicated that the presence of Pb(Zn1/3Ta2/3)O3 (PZnTa) in the solid solution decreased the structural stability of overall perovskite phase.Atransition fromtetragonal to pseudo-cubic symmetry was observed as the PZnTa content increased and a co-existence of tetragonal and pseudo-cubic phaseswas observed at a composition close to x = 0.1. Examination of the dielectric spectra indicated that PZT–PZnTa exhibited an extremely high relative permittivity at the MPB composition. The permittivity showed a ferroelectric to paraelectric phase transition at 330 C with a maximum value of 19,600 at 100 Hz at the MPB composition.