Title of article
Catalytic Transfer Hydrogenation of Ketones with KHCr(CO)5/HCO2H/Et3N Systems
Author/Authors
Brunet، Jean-Jacques نويسنده , , Chauvin، Remi نويسنده , , Leglaye، Pascale نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-712
From page
713
To page
0
Abstract
In the presence of a HCO2H/Et3N (1:1) mixture, KHCr(CO)5 is an efficient catalyst precursor for the transfer hydro-genation of ketones in THF at room temperature. KHCr(CO)5 is also a stoichiometric reagent for the selective reduction of the carboncarbon double bond of (alpha),(beta)-unsaturated ketones.
Keywords
Chromates , Hydrogenations , Reductions , (alpha),(beta)-Unsaturated ketones , asymmetric synthesis , Catalytic transfer hydrogenation
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Serial Year
1999
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Record number
83568
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