Hydrothermal synthesis, crystal structures and luminescent properties of two new Ln(III)–succinate (LnZEu, Tb) complexes exhibiting three dimensional networks

Two new coordination polymers, [Eu2(L)3(H2O)2]n 1 and {[Tb2(L)3(H2O)2]$H2O}n 2, (H2LZsuccinic acid) have been synthesized by the reaction of H2L with nitrate salts of Eu(III) or Tb(III) under hydrothermal conditions. The X-ray diffraction analysis reveals that the two complexes are constructed by L bridging the chains of edge-sharing EuO8(H2O) or TbO8(H2O) polyhedra to form 3D network structure. 1 and 2 possess different topological structures due to the difference in the conformations of L. The solid photoluminescence of 1 and 2 was also investigated in room temperature. q 2005 Elsevier B.V. All rights reserved